Product ID:FPPF GLYCLEAN ANTIFREEZE EXTENDER
MSDS Date:07/07/1998
FSC:4330
NIIN:01-387-1370
Status Code:A
MSDS Number: CLQBR

FPPF CHEMICAL CO INC

117 WEST TUPPER STREET
BUFFALO, NY 14201-2193
US

Emergency Phone: 800-424-9300

Info Phone: 800-735-3773

Preparer: ERNEST CARTER

Cage: 020D9

FPPF CHEMICAL CO INC

BUFFALO, NY 14201-2193 US

Telephone: 800-735-3773

Cage: 020D9

SODIUM HYDROXIDE

CAS: 1310-73-2

RTECS: WB4900000

OSHA PEL 2 MG/M3

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

SODIUM NITRITE

CAS: 7632-00-0

RTECS: RA1225000

OSHA PEL 2 MG/M3

ACGIH TLV: 2 MG/M3

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Health Hazards Acute and Chronic:EYE CONTACT: CAUSES SEVERE BURNS. SKIN
CONTACT: CORROSIVE ACTION CAUSES BURNS AND FREQUENTLY DEEP
ULCERATION WITH SUBSEQUENT SCARRING. INHALATION: VAPORS CAN
IRRITATE NOSE, THROAT, AND CAUSE DAMAGE T O THE UPPER RESPIRATORY
TRACT. LARGE AMOUNTS MAY CAUSE SYSTEMIC EFFECTS, AS NITRATES ARE
ABSORBED BY LUNG TISSUE. NAUSEA, VOMITING, DIZZINESS, HEADACHE,
BLURRED VISION. INGESTION: CAN CAUSE VERY SERIO US DAMAGE TO THE
MUCOUS MEMBRANES OR OTHER TISSUES WITH WHICH CONTACT IS MADE, AND
MAY BE FATAL.
Effects of Overexposure:EYES: CAUSES SEVERE BURNS AND IRRITATION.
DERMAL: CORROSIVE. IRRITATION, BURNS. INHALATION: VAPORS MAY
IRRITATE NOSE, THROAT, RESPIRATORY TRACT.LARGE AMOUNTS MAY CAUSE
SYSTEMIC EFFECTS, AS NITRITES AR E READILY ABSORBED BY LUNG
TISSUE.NAUSEA, VOMITING, DIZZINESS, HEADACHE, BLURRED
VISION.INGESTION: NAUSEA, VOMITING, DIZZINESS, HEADACHE, BLURRED
VISION.

First Aid:EYES: FLUSH WITH LARGE AMOUNTS OF WATER FOR 15 MINUTES,
HOLDING EYELIDS OPEN DURING FLUSHING WITH WATER.GET MEDICAL
ATTENTION. DERMAL: WASH WITH SOAP AND WATER AND THEN FLUSH WITH
WATER UNTIL ALL CHEM ICAL IS REMOVE.REMOVE CONTAMINATED CLOTHING
PROMPTLY AND WASH BEFORE REUSE. IF IRRITATION PERSISTS, GET MEDICAL
ATTENTION.INHALATION: REMOVE TO FRESH AIR. GET PROMPT MEDICAL
ATTENTION. INGESTION: IF C ONSCIOUS, DRINK LARGE AMOUNTS OF WATER
OR ACIDIC BEVERAGES (TOMATO OR ORANGE JUICE, CARBONATED SOFT
DRINKS). NOT NOT INDUCE VOMITING.

Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL.
Fire Fighting Procedures:USE NIOSH APPROVED SELF CONTAINED BREATHING
APPARATUS. CONTACT WITH SOME METALS, PARTICULARLY MAGNESIUM,
ALUMINUM AND ZINC (GALVANIZED) CAN RAPIDLY GENERATE HYDROGEN, WHICH
IS EXPLOSIVE.
Unusual Fire/Explosion Hazard:MATERIAL IS AN OXIDIZING AGENT AND CAN
SUPPLY OXYGEN TO STIMULATE OR ACCELERATE COMBUSTION OF ORGANIC OR
OTHER COMBUSTION OF ORGANIC OR OTHER COMBUSTIBLE MATERIALS. HEATING
OF NON-VENTED CONTAINER MAY CAUSE EXPLOSION. KEEP SURROUNDING
CONTAINERS COOL WITH WATER SPRAY.

Spill Release Procedures:ONLY TRAINED PERSONNEL WITH NIOSH/MSHA
APPROVED COMBINATION DUST/VAPOR AND ACID GAS RESPIRATORS SHOULD BE
PERMITTEDINAREA.DILUTE SPILL WITH LARGE AMOUNTS OF WATER AND USE
VACUUM TRUCK TO PICK UP DILUT ED MATERIAL FOR PROPER DISPOSAL.
ATTEMPT TO KEEP OUT OF SEWER. ANY RELEASE OF THIS PRODUCT TO THE
ENVIRONMENT MAY SUBJECT TO FEDERAL AND/OR STATE REPORTING
REQUIREMENTS. CHECK WITH APPRORIATE AGENIES.

Respiratory Protection:USE A RESPIRATOR APPROVED BY NIOSH FOR PRODUCT
DUSTS OR SOLUTION MISTS-OR NITROGEN OXIDE GASES-AS APPLICABLE. SOME
EXPOSURE MAY REQUIRE NIOSH APPROVED, SELF CONTAINED BREATHING
APPARATUS OR AN AIR SUP PLIED RESPIRATOR.
Ventilation:MECHANICAL TO MAINTAIN GOOD AIR FLOW.
Protective Gloves:RUBBER.
Eye Protection:GOGGLES OR SAFETY GLASSES.
Other Protective Equipment:WEAR FULL WORK CLOTHING AS NEEDED TO
MINIMIZE EXPOSURE.
Work Hygienic Practices:ALWAYS WASH FACE AND HANDS AFTER CONTACT.
REMOVE CONTAMINATED CLOTHING AND WASH BEFORE REUSE.
Supplemental Safety and Health

HCC:B1
Spec Gravity:1.09 @ 25 C
pH:13.5
VOC Grams/Liter:8.95
Viscosity:25 C: LESS THAN 10CPS
Evaporation Rate & Reference:<1
Solubility in Water:COMPLETE
Appearance and Odor:YELLOW CLEAR LIQUID

Stability Indicator/Materials to Avoid:YES
HAZARDOUS AND VIOLENT REACTIONS CAN OCCUR WITH ACIDS, AMMONIUM
COMPOUNDS, REDUCING AGENTS - PARTICULARLY CYANIDES, THIOCYANATES,
THIOSULFATES, COMBUSTIBLES, ORGANICS. SODIUM HYDROXIDE REACTS WITH
MAGNESIUM AND BRONZE TO GEN
Stability Condition to Avoid:TEMPERATURES ABOVE 320 C DECOMPOSES TO
YIELD OXIDES OF NITROGEN, WHICH ARE TOXIC AND ARE ALSO OXIDIZERS.
Hazardous Decomposition Products:TOXIC, GASEOUS NITROGEN OXIDES, WHICH
ARE OXIDIZERS: CARBON MONOXIDE AND OTHER ORGANIC COMPOUNDS.
Conditions to Avoid Polymerization:WILL NOT OCCUR.

Waste Disposal Methods:IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL
LAWS.

Toxicological Information:CHRONIC HEALTH HAZARDS: NONE IS EXPECTED AT
THE INDUSTRIAL LEVEL. SAFE HANDLING OF THIS MATERIAL ON A LONG-TERM
BASIS SHOULD EMPHASIZE THE AVOIDANCE OF ALL EFFECTS FROM
REPETTITIVE ACUTE EXPOSURE.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:ANY RELEASE OF THIS PRODUCT TO THE ENVIRONMENT MAY SUBJECT
TO FEDERAL AND/OR STATE REPORTING REQUIREMENTS. CHECK WITH
APPROPRIATE AGENCIES.

Transport Information:US DOT SHIPPING NAME: CORROSIVE LIQUID, N.O.S.
TECHNICAL NAMES: (SODIUM HYDROXIDE, SODIUM NITRITE). US DOT PRIMARY
HAZARD CLASS: 8 (CORROSIVE). US DOT SECONDARY HAZARD CLASS: NONE.
IDENTIFICATION NUMB ER: UN1760. PACKING GROUP: III. REPORTABLE
QUANTITY: NONE IN 55-GALLON DRUMS.

SARA Title III Information:NO DATA PROVIDED BY MANUFACTURER
Federal Regulatory Information:NO DATA PROVIDED BY MANUFACTURER
State Regulatory Information:NO DATA PROVIDED BY MANUFACTURER